Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main202229 Jul 2022Morning ShiftChemistryChemical KineticsActual

The reaction between X and Y is first order with respect to X and zero order with respect to Y . Experiment X molL - 1 Y molL - 1 Initial rate mol L - 1 min - 1 I 0 . 1 0 . 1 2 × 10 - 3 II L 0 . 2 4 × 10 - 3 III 0 . 4 0 . 4 M × 10 - 3 IV 0 . 1 0 . 2 2 × 10 - 3 Examine the data of table and calculate ratio of numerical values of M and L .

Correct answer

40

Step-by-step solution

Given that reaction is first order with respect to X and of zero order with respect to Y. Means r = k X Y 0 Where k = rate constant. Using data I & II 4 × 10 - 3 2 × 10 - 3 = L 0 . 1 0 . 2 0 . 1 0 ⇒ L = 0 . 2 Using data from I & III M × 10 - 3 2 × 10 - 3 = 0 . 4 0 . 1 ⇒ M = 8 Not the ratio which is asked in question M L = 8 0 . 2 = 40

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

For a reversible reaction R P , at constant temperature, both the forward and the backward reactions are first order elementary reactions with rate constants k_f and k_b , respecti 2026For a first-order reaction R P at a given temperature, k is the rate constant. For this reaction, at the given temperature, the concentrations of R and P at a time t are [ R ] and 2026Given below are two statements: R=8.314 J K ⁻¹ mol ⁻¹ and 1 cal =4.2 J Statement I: When E_a=12.6 kcal/mol, the room temperature rate constant is doubled by a 10 ,^ C increase in t 2026Decomposition of a hydrocarbon follows the equation k = (5.5 10¹¹ , s ⁻¹) ,e^ -28000 , K T . The activation energy of reaction is __________ kJ mol ⁻¹ . (Nearest Integer) Given : R 2026For a reaction A P at T K , the half life (t_ 1/2 ) is plotted as a function of initial concentration [A]₀ of A as given below. The value of x in the given figure is _______ s (Nea 2026First order gas phase reaction A B + C p_i = initial pressure of gas A, p_t = total pressure of the reaction mixture at time t Expression of rate constant ( k ) is 2026If the half life of a first order reaction is 6.93 minutes then the time required for completion of 99 % of the reaction will be _____ minutes. (Given : 2 = 0.3010 ) 2026Consider the given graph showing variation of reactant concentration with time. Three different reactions were started with identical initial concentration of reactants. Which of t 2026 Full Chemical Kinetics list All JEE Main PYQs