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JEE Main 202229 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 29 July · Morning Shift · Chemistry · Chemical Kinetics

The reaction between X and Y is first order with respect to X and...

The reaction between XX and YY is first order with respect to XX and zero order with respect to YY.

Experiment [X]molL−1\dfrac{\left[X\right]}{{molL}^{- 1}} [Y]molL−1\dfrac{\left[Y\right]}{{molL}^{- 1}} InitialratemolL−1min⁡−1\dfrac{Initial rate}{mol{L}^{- 1}\min^{- 1}}
I 0.10 . 1 0.10 . 1 2×10−32 \times {10}^{- 3}
II LL 0.20 . 2 4×10−34 \times {10}^{- 3}
III 0.40 . 4 0.40 . 4 M×10−3M \times {10}^{- 3}
IV 0.10 . 1 0.20 . 2 2×10−32 \times {10}^{- 3}

Examine the data of table and calculate ratio of numerical values of MM and LL.

Correct answer

40

Step-by-step solution

Given that reaction is first order with respect to X and of zero order with respect to Y.

Means r=kr = k\left[X\right]{\left[Y\right]}^{0} Where k = rate constant.

Using data II & IIII

4×10−32×10−3=(L0.1)(0.20.1)0⇒L=0.2\dfrac{4 \times {10}^{- 3}}{2 \times {10}^{- 3}} = \left(\dfrac{L}{0 . 1}\right){\left(\dfrac{0 . 2}{0 . 1}\right)}^{0} ⇒ L = 0 . 2

Using data from II & IIIIII

M×10−32×10−3=0.40.1⇒M=8\dfrac{M \times {10}^{- 3}}{2 \times {10}^{- 3}} = \dfrac{0 . 4}{0 . 1} ⇒ M = 8

Not the ratio which is asked in question

ML=80.2=40\dfrac{M}{L} = \dfrac{8}{0 . 2} = 40

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