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JEE Main 202228 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 28 July · Evening Shift · Chemistry · Chemical Kinetics

For a reaction, given below is the graph of lnkvs(1)/(T) . The...

For a reaction, given below is the graph of lnkvs1Tlnkvs\dfrac{1}{T}. The activation energy for the reaction is equal to____calmol−1cal{mol}^{- 1}.(Given : R=2calK−1mol−1R = 2{calK}^{- 1}{mol}^{- 1})

For a reaction, given below is the graph of lnkvs(1)/(T) . The activation energy for the reaction is equal to____ cal

Correct answer

0

Step-by-step solution

Arrhenius suggested an equation which describes rate constant,kk as a function of temperature, T.

k=Ae−Ea/RTk = {Ae}^{- Ea / RT}

A=frequency factor

Ea=Activationenergy{E}_{a} = Activationenergy

In the Arrhenius equation the factor e−Ea/RTe{}^{- Ea / RT}corresponds to the fraction of molecules that have kinetic energy greater than Ea

lnk=−Ea+lnAlnk = \dfrac{-}{Ea} + lnA

Y=C+MXY = C + MX

On plotting lnkagainst1/Tlnkagainst1 / T we get a straight line.The slope of the graph gives activation energy and intercept gives frequency factor

For a reaction, given below is the graph of lnkvs(1)/(T) . The activation energy for the reaction is equal to____ cal

slope= - \dfrac{Ea}{R} = \dfrac{-}{Δy}

Slope =EaR=205= \dfrac{Ea}{R} = \dfrac{20}{5}

Ea=4R=8Cal/mol{E}_{a} = 4R = 8Cal / mol

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