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JEE Main 202227 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 27 July · Evening Shift · Chemistry · Chemical Kinetics

cases [A] & → & [B] Reactant & & Product cases If formation of...

{[A]→[B]ReactantProduct\begin{cases}\left[A\right] & \to & \left[B\right] \\ Reactant & & Product\end{cases}

If formation of compound \left[B\right]followsthefirstorderofkineticsandafterfollows the first order of kinetics and after70minutestheconcentrationof[A]minutes the concentration of \left[A\right] was found to be half of its initial concentration. Then the rate constant of the reaction is x×10−6s−1x \times {10}^{- 6}{s}^{- 1}. The value of xx is____

Correct answer

0

Step-by-step solution

{[A]→[B]ReactantProduct\begin{cases}\left[A\right] & \to & \left[B\right] \\ Reactant & & Product\end{cases}

Since the reaction follows the first order kinetics and after 7070 minutes the concentration of \left[A\right]wasfoundtobehalfofitsinitialconcentration.Thatmeans70minutesisthehalflifetimeforthereaction.Andweknowthatforafirstorderreactionhalflifetimeisgivenas.</p><p>was found to be half of its initial concentration. That means 70 minutes is the half life time for the reaction. And we know that for a first order reaction half life time is given as.</p><p>t\dfrac{1}{2} = \dfrac{0 . 693}{K}K = \dfrac{0 . 693}{{t}_{\dfrac{1}{2}}} = \dfrac{0 . 693}{70 \times 60sec .}</p><p></p><p>= \dfrac{6930}{7 \times 6} \times {10}^{- 6}\sec^{- 1} = 165 \times {10}^{- 6}\sec^{- 1}So, x = 165

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