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JEE Main 202228 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 28 July · Morning Shift · Chemistry · Chemical Kinetics

For the given first order reaction A → B the half life of the...

For the given first order reaction A→BA \to B the half life of the reaction is 0.3010min0 . 3010min. The ratio of the initial concentration of reactant to the concentration of reactant at time 2.0min2 . 0min will be equal to _____. (Nearest integer)

Correct answer

0

Step-by-step solution

Given A→BA \to B is a first order reaction

and t12=0.3010mint\dfrac{1}{2} = 0 . 3010min

AoAt\dfrac{{A}_{o}}{{A}_{t}} at time 2min=2min =?

We know the integrated rate equation for first order reaction

K=2.303tlog⁡[A0At]K = \dfrac{2 . 303}{t}\log \left[\dfrac{{A}_{0}}{{A}_{t}}\right]

⇒0⋅693t12=2⋅303tlog⁡(A0At)⇒0⋅6930.3010min=2⋅3032minlog⁡(A0At)⇒ \dfrac{0 \cdot 693}{t\dfrac{1}{2}} = \dfrac{2 \cdot 303}{t}\log \left(\dfrac{{A}_{0}}{{A}_{t}}\right) ⇒ \dfrac{0 \cdot 693}{0 . 3010min} = \dfrac{2 \cdot 303}{2min}\log \left(\dfrac{{A}_{0}}{{A}_{t}}\right)

logA0At=2log\dfrac{{A}_{0}}{{A}_{t}} = 2

∴A0At=102=100∴ \dfrac{{A}_{0}}{{A}_{t}} = {10}^{2} = 100

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