Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202226 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
26 July
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 26 July · Evening Shift · Chemistry · Chemical Kinetics

At 30 ° C , the half life for the decomposition of AB _ 2 is 200s...

At 30°C30 ° C, the half life for the decomposition of AB2{AB}_{2} is 200s200s and is independent of the initial concentration of AB2{AB}_{2}. The time required for 8080 % of the AB2{AB}_{2} to decompose is (Given: log⁡2=0.30\log 2 = 0 . 30; log⁡3=0.48\log 3 = 0 . 48)

Options

  1. A200s200s
  2. B323s323s
  3. C467s467s
  4. D532s532s

Correct answer

C. 467s467s

Step-by-step solution

Since half life is independent of intial concentration of the reactant, it's a first order reaction

k=ln⁡2t12k = \dfrac{\ln 2}{t\dfrac{1}{2}}
kt=2.303logA0Akt = 2 . 303log\dfrac{{A}_{0}}{A}

ln⁡2t12t=2.303logA0A\dfrac{\ln 2}{t\dfrac{1}{2}}t = 2 . 303log\dfrac{{A}_{0}}{A}

2.303log⁡2200t=2.303log10020\dfrac{2 . 303\log 2}{200}t = 2 . 303log\dfrac{100}{20}

t=2000.3×log⁡5=466.67sec≈467sect = \dfrac{200}{0 . 3} \times \log 5 = 466 . 67sec \approx 467sec

Practice Chemical Kinetics on Quantrex Academy →

More from Chemical Kinetics

For a reversible reaction R leftharpoons P , at constant temperature, both the forward… JEE Advanced 2026For a first-order reaction R P at a given temperature, k is the rate constant. For this… JEE Advanced 2026Given below are two statements: R=8.314 J K ^ -1 mol ^ -1 and 1 cal =4.2 J Statement I… JEE Main 2026Decomposition of a hydrocarbon follows the equation k = (5.5 × 10^ 11 \,s^ -1 )\,e^… JEE Main 2026For a reaction A arrow P at T K , the half life (t_ 1/2 ) is plotted as a function of… JEE Main 2026First order gas phase reaction A arrow B + C p_i = initial pressure of gas A, p_t = total… JEE Main 2026If the half life of a first order reaction is 6.93 minutes then the time required for… JEE Main 2026Consider the given graph showing variation of reactant concentration with time. Three… JEE Main 2026 Full Chemical Kinetics list All JEE Main PYQs