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JEE Main 202225 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
25 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2022 · 25 June · Morning Shift · Chemistry · Chemical Kinetics

For a given chemical reaction γ _ 1 A + γ _ 2 B → γ _ 3 C + γ _ 4 D...

For a given chemical reaction γ1A+γ2B→γ3C+γ4D{\gamma}_{1}A + {\gamma}_{2}B \to {\gamma}_{3}C + {\gamma}_{4}D. Concentration of CC changes from 10mmoldm−310mmol{dm}^{- 3} to 20mmoldm−320mmol{dm}^{- 3} in 10s.10s . Rate of appearance of DD is 1.51 . 5 times the rate of disappearance of BB which is twice the rate of disappearance AA. The rate of appearance of DD has been experimentally determined to be 9mmoldm−3s−1.9mmol{dm}^{- 3}{s}^{- 1} . Therefore the rate of reaction is____mmoldm−3s−1.mmol{dm}^{- 3}{s}^{- 1} . (Nearest Integer)

Correct answer

0

Step-by-step solution

\dfrac{d\left[c\right]}{dt} = \left(\dfrac{20 - 10}{10}\right) = 1milimole / {dm}^{3}sec</p><p></p><p>{\gamma}_{1}A + {\gamma}_{2}B \to {\gamma}_{3}C + {\gamma}_{4}D</p><p></p><p>\dfrac{d\left[D\right]}{dt} = 1 . 5\left(- \dfrac{d}{dt}\left[B\right]\right) = 9milimole / {dm}^{3}sec</p><p>(−ddt[B])=2(−ddt[A])</p><p>\left(- \dfrac{d}{dt}\left[B\right]\right) = 2\left(- \dfrac{d}{dt}\left[A\right]\right)

Rate =−1γ1d[A]dt=−1γ2d[B]dt=1γ3d[C]dt=1γ4d[D]dt= - \dfrac{1}{{\gamma}_{1}}\dfrac{d\left[A\right]}{dt} = - \dfrac{1}{{\gamma}_{2}}\dfrac{d\left[B\right]}{dt} = \dfrac{1}{{\gamma}_{3}}\dfrac{d\left[C\right]}{dt} = \dfrac{1}{{\gamma}_{4}}\dfrac{d\left[D\right]}{dt}

(i) d[D]dt=γ4γ2[−d[B]dt]=1.5(−ddt[B])\dfrac{d\left[D\right]}{dt} = \dfrac{{\gamma}_{4}}{{\gamma}_{2}}\left[- \dfrac{d\left[B\right]}{dt}\right] = 1 . 5\left(- \dfrac{d}{dt}\left[B\right]\right)

γ4γ2=1.5\dfrac{{\gamma}_{4}}{{\gamma}_{2}} = 1 . 5

(ii) γ2γ1[−d[A]dt]=(−ddt[B])=2(−ddt[A])\dfrac{{\gamma}_{2}}{{\gamma}_{1}}\left[- \dfrac{d\left[A\right]}{dt}\right] = \left(- \dfrac{d}{dt}\left[B\right]\right) = 2\left(- \dfrac{d}{dt}\left[A\right]\right)

γ2γ1=2\dfrac{{\gamma}_{2}}{{\gamma}_{1}} = 2

(iii) d[C]dt=γ3γ4[d[D]dt]\dfrac{d\left[C\right]}{dt} = \dfrac{{\gamma}_{3}}{{\gamma}_{4}}\left[\dfrac{d\left[D\right]}{dt}\right]

1=γ3γ4×91 = \dfrac{{\gamma}_{3}}{{\gamma}_{4}} \times 9

γ4γ3=9\dfrac{{\gamma}_{4}}{{\gamma}_{3}} = 9

So, if

γ3=1thanγ4=9γ2=6andγ1=3Rateofreaction=1γ3d[C]dt=1mmoldm−3s−1{\gamma}_{3} = 1than{\gamma}_{4} = 9{\gamma}_{2} = 6and{\gamma}_{1} = 3Rateofreaction = \dfrac{1}{{\gamma}_{3}}\dfrac{d [ C ]}{dt} = 1mmol{dm}^{- 3}{s}^{- 1}

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