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JEE Main 20205 SeptemberMorning Shift
Exam
JEE Main
Year
2020
Date
5 September
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Kinetics

JEE Main 2020 · 5 September · Morning Shift · Chemistry · Chemical Kinetics

A flask contains a mixture of compounds A and B . Both compounds...

A flask contains a mixture of compounds AA and BB. Both compounds decompose by first-order kinetics. The half-lives for AA and BB are 300s300s and 180s180s, respectively. If the concentrations of AA and BB are equal initially, the time required for the concentration of A to be four times that of BB (in s) is : (Useln2=0.693)( Useln2 = 0 . 693 )

Options

  1. A180180
  2. B900900
  3. C300300
  4. D120120

Correct answer

B. 900900

Step-by-step solution

{C}_{t} = {C}_{0}{e}^{- kt}</p><p></p><p>{k}_{A} = \dfrac{\ln 2}{300}(k=ln⁡2T1/2)\left(k = \dfrac{\ln 2}{{T}_{1/2}}\right)

kB=ln⁡2180{k}_{B} = \dfrac{\ln 2}{180}

(Ct)A=(C0)Ae−kAt{\left({C}_{t}\right)}_{A} = {\left({C}_{0}\right)}_{A}{e}^{- {k}_{A}t}

(Ct)B=(C0)Be−kBt{\left({C}_{t}\right)}_{B} = {\left({C}_{0}\right)}_{B}{e}^{- {k}_{B}t}

(Ct),B(Ct),A=(C0),B(C0),A×e(kA−kB)t\dfrac{{\left({C}_{t}\right)}_{, B}}{\left({C}_{t}\right), A} = \dfrac{{\left({C}_{0}\right)}_{, B}}{\left({C}_{0}\right), A} \times {e}^{\left({k}_{A} - {k}_{B}\right)t}

14=e(kA−kB)t\dfrac{1}{4} = {e}^{\left({k}_{A} - {k}_{B}\right)t}

ln14=[ln⁡2300−ln⁡2180]tln\dfrac{1}{4} = \left[\dfrac{\ln 2}{300} - \dfrac{\ln 2}{180}\right]t

−2ln⁡2=[ln⁡2300−ln⁡2180]t- 2\ln 2 = \left[\dfrac{\ln 2}{300} - \dfrac{\ln 2}{180}\right]t

2=(120180×300)t2 = \left(\dfrac{120}{180 \times 300}\right)t

t=2×180×300120=900sect = \dfrac{2 \times 180 \times 300}{120} = 900sec

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