JEE Main 201816 AprilOnline
- Exam
- JEE Main
- Year
- 2018
- Date
- 16 April
- Mode
- Online
- Subject
- Chemistry
- Chapter
- Chemical Kinetics
JEE Main 2018 · 16 April · Online · Chemistry · Chemical Kinetics
If 50 % of a reaction occurs in 100 second and 75 % of the reaction...
If 50 % of a reaction occurs in 100 second and 75 % of the reaction occurs in 200 second, the order of this reaction is:
Options
- A2
- B3
- CZero
- D1
Correct answer
D. 1
Step-by-step solution
50% of a reaction occurs in 100 second and 75% of the reaction occurs in 200 second, the order of this reaction is 1.
Let the initial reactant concentration is 1 M.
In the first 100 seconds, reactant concentration is reduced to
In the second 100 seconds (total 200 seconds from start), reactant concentration is reduced to .
Thus, we observe that after each 100 second period, the reactant concentration is reduced to one half. Hence, 100 seconds is the half-life period and is independent of reactant concentration. This is characteristic of the first-order reaction.
First-order reaction as the half-life is constant.