Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202623 JanuaryEvening Shift
Exam
JEE Main
Year
2026
Date
23 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2026 · 23 January · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given below are two statements: Statement I : The second ionisation...

Given below are two statements:
Statement I: The second ionisation enthalpy of Na is larger than the corresponding ionisation enthalpy of Mg.
Statement II: The ionic radius of O2−\mathrm{O}^{2-} is larger than that of F−\mathrm{F}^{-}.
In the light of the above statements, choose the correct answer from the options given below

Options

  1. AStatement I is false but Statement II is true
  2. BBoth Statement I and Statement II are false
  3. CStatement I is true but Statement II is false
  4. DBoth Statement I and Statement II are true

Correct answer

D. Both Statement I and Statement II are true

Step-by-step solution

Statement I examines second ionization enthalpy:
Na (1s2^2 2s2^2 2p6^6 3s1^1) loses its first electron to achieve a stable noble gas configuration. The second ionization would break into the 2p core, requiring enormous energy.
Mg (1s2^2 2s2^2 2p6^6 3s2^2) loses its second electron from the 3s orbital, which is less stable.
Thus, IE2_2 of Na is much larger than IE2_2 of Mg.
Statement I is TRUE.
Statement II compares O2−^{2-} and F−^-:
both are isoelectronic with 10 electrons.
O2−^{2-} has 8 protons while F−^- has 9 protons.
The lower nuclear charge in O2−^{2-} results in weaker electrostatic attraction, making the ionic radius of O2−^{2-} larger than F−^-.
Statement II is TRUE.
Practice Classification of Elements and Periodicity in Properties on Quantrex Academy →

More from Classification of Elements and Periodicity in Properties

The correct statement(s) regarding the periodic properties of elements is(are) JEE Advanced 2026Match List-I with List-II. List-I Electronic configuration of neutral atom (where n=2 )… JEE Main 2026In a period, the first ionisation enthalpy of the element at extreme left and the… JEE Main 2026Given below are two statements: Statement I: Aluminium is more electropositive than… JEE Main 2026Given below are two statements : Statement I: The number of pairs among [Al_2O_3… JEE Main 2026Given below are two statements: Statement I: The correct order of electronegativity of… JEE Main 2026The 1^ st ionization enthalpy for Mg is +737 kJ/mol. The most probable estimated value of… JEE Main 2026The electronegativity of a group 13 element 'E' is same as that of Ge (on Pauling scale… JEE Main 2026 Full Classification of Elements and Periodicity in Properties list All JEE Main PYQs