JEE Main 202623 JanuaryEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 23 January
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- Classification of Elements and Periodicity in Properties
JEE Main 2026 · 23 January · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties
Given below are two statements: Statement I : The second ionisation...
Given below are two statements:
Statement I: The second ionisation enthalpy of Na is larger than the corresponding ionisation enthalpy of Mg.
Statement II: The ionic radius of is larger than that of .
In the light of the above statements, choose the correct answer from the options given below
Statement I: The second ionisation enthalpy of Na is larger than the corresponding ionisation enthalpy of Mg.
Statement II: The ionic radius of is larger than that of .
In the light of the above statements, choose the correct answer from the options given below
Options
- AStatement I is false but Statement II is true
- BBoth Statement I and Statement II are false
- CStatement I is true but Statement II is false
- DBoth Statement I and Statement II are true
Correct answer
D. Both Statement I and Statement II are true
Step-by-step solution
Statement I examines second ionization enthalpy:
Na (1s 2s 2p 3s) loses its first electron to achieve a stable noble gas configuration. The second ionization would break into the 2p core, requiring enormous energy.
Mg (1s 2s 2p 3s) loses its second electron from the 3s orbital, which is less stable.
Thus, IE of Na is much larger than IE of Mg.
Statement I is TRUE.
Statement II compares O and F:
both are isoelectronic with 10 electrons.
O has 8 protons while F has 9 protons.
The lower nuclear charge in O results in weaker electrostatic attraction, making the ionic radius of O larger than F.
Statement II is TRUE.
Na (1s 2s 2p 3s) loses its first electron to achieve a stable noble gas configuration. The second ionization would break into the 2p core, requiring enormous energy.
Mg (1s 2s 2p 3s) loses its second electron from the 3s orbital, which is less stable.
Thus, IE of Na is much larger than IE of Mg.
Statement I is TRUE.
Statement II compares O and F:
both are isoelectronic with 10 electrons.
O has 8 protons while F has 9 protons.
The lower nuclear charge in O results in weaker electrostatic attraction, making the ionic radius of O larger than F.
Statement II is TRUE.