JEE Main202621 January 2026Evening ShiftChemistryClassification of Elements and Periodicity in PropertiesActual
Given below are two statements : Statement I : The correct order in terms of atomic/ionic radii is Al > Mg > Mg ²⁺> Al ³⁺ . Statement II : The correct order in terms of the magnitude of electron gain enthalpy is Cl > Br > S > O . In the light of the above statements, choose the correct answer from the options given below :
Options
- ABoth Statement I and Statement II are false
- BBoth Statement I and Statement II are true
- CStatement I is false but Statement II is true
- DStatement I is true but Statement II is false
Correct answer
C. Statement I is false but Statement II is true
Step-by-step solution
Analyzing Statement I: The order given is Al > Mg > Mg²⁺ > Al³⁺. However, the correct atomic radii order should be Mg > Al because Mg is in group 2 (period 3) while Al is in group 13 (period 3), and moving right across a period decreases radius. The correct order would be Mg > Al > Mg²⁺ > Al³⁺. Therefore, Statement I is FALSE. Analyzing Statement II: Electron gain enthalpy magnitudes follow: Cl (highest, ~349 kJ/mol) > Br (~325) > S (~200) > O (~141). This is because Cl has the highest tendency to gain an electron