JEE Main202228 Jul 2022Morning ShiftChemistryClassification of Elements and Periodicity in PropertiesActual
In which of the following pairs, electron gain enthalpies of constituent elements are nearly the same or identical? (A) Rb and Cs (B) Na and K (C) Ar and Kr (D) I and At Choose the correct answer from the options given below
Options
- AA   &   B only
- BB   &   C only
- CA   &   C only
- DC   &   D only
Correct answer
C. A   &   C only
Step-by-step solution
Rb   &   Cs have nearly same electron gain enthalpy Their values are nearly = - 46   kJ / mol Ar   &   Kr also have same ΔH e . g . . Value is + 96   kJ / mol . Na   and   K have different values ( - 53   and   - 48   kJ / mol )   . And I   and   At   has   values   of   - 295   and   - 270   kJ / mol . As we move down the group value of electron gain enthalpy decreases, with few exceptions.