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JEE Main 202228 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
28 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2022 · 28 July · Morning Shift · Chemistry · Classification of Elements and Periodicity in Properties

In which of the following pairs, electron gain enthalpies of...

In which of the following pairs, electron gain enthalpies of constituent elements are nearly the same or identical?

(A) RbRb and CsCs

(B) Na and KK

(C) ArAr and KrKr

(D) II and AtAt

Choose the correct answer from the options given below

Options

  1. AA and BA \text{ and } B only
  2. BB and CB \text{ and } C only
  3. CA and CA \text{ and } C only
  4. DC and DC \text{ and } D only

Correct answer

C. A and CA \text{ and } C only

Step-by-step solution

Rb and CsRb \text{ and } Cs have nearly same electron gain enthalpy Their values are nearly =−46kJ/mol= - 46kJ / mol

Ar and KrAr \text{ and } Kr also have same ΔHe.g.{\Delta H}_{e . g .}. Value is +96kJ/mol+ 96kJ / mol.

NaandKNaandK have different values (−53and−48kJ/mol)( - 53and - 48kJ / mol ). And IandAthasvaluesof−295and−270kJ/molIandAthasvaluesof - 295and - 270kJ / mol.

As we move down the group value of electron gain enthalpy decreases, with few exceptions.

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