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JEE Main 202229 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
29 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2022 · 29 June · Evening Shift · Chemistry · Classification of Elements and Periodicity in Properties

Given below are two statements. One is labelled as Assertion A and...

Given below are two statements. One is labelled as
Assertion AA and the other is labelled as Reason RR.
Assertion AA : The first ionization enthalpy for oxygen is lower than that of nitrogen.

Reason RR : The four electrons in 2p2p orbitals of oxygen experience more electron-electron repulsion.

In the light of the above statements, choose the correct answer from the options given below.

Options

  1. ABoth AA and RR are correct and RR is the correct explanation of AA.
  2. BBoth AA and RR are correct but RR is NOT the correct explanation of AA.
  3. CAA is correct but RR is not correct.
  4. DAA is not correct but RR is correct

Correct answer

A. Both AA and RR are correct and RR is the correct explanation of AA.

Step-by-step solution

Ionization energy of oxygen is less than that of nitrogen because 2p2p subshell of nitrogen is half filled, and half filled orbitals have some extra stability, so removing electrons from them will be little more difficult.
And In oxygen atom, 22 of the four2pfour2p electrons must occupy the same 2p2p orbital resulting in an increased electron electron-repulsion.

N=1s22s22p3N = 1{s}^{2}2{s}^{2}2{p}^{3}

O=1s22s22p4O = 1{s}^{2}2{s}^{2}2{p}^{4}

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