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JEE Main 2007
Exam
JEE Main
Year
2007
Subject
Chemistry
Chapter
Classification of Elements and Periodicity in Properties

JEE Main 2007 · Chemistry · Classification of Elements and Periodicity in Properties

The stability of dihalides of Si, Ge, Sn and Pb increases steadily...

The stability of dihalides of Si,Ge,Sn\mathrm{Si}, \mathrm{Ge}, \mathrm{Sn} and Pb\mathrm{Pb} increases steadily in the sequence

Options

  1. AGeX2≪SiX2≪SnX2≪PbX2\mathrm{GeX}_2 \ll \mathrm{SiX}_2 \ll \mathrm{SnX_2} \ll \mathrm{PbX}_2
  2. BSiX2≪GeX2≪PbX2≪SnX2\mathrm{SiX}_2 \ll \mathrm{GeX}_2 \ll \mathrm{PbX}_2 \ll \mathrm{SnX}{ }_2
  3. CSiX2≪GeX2≪SnX2≪PbX2\mathrm{SiX}_2 \ll \mathrm{GeX}_2 \ll \mathrm{SnX}_2 \ll \mathrm{PbX}_2
  4. DPbX2≪SnX2≪GeX2≪SiX2\mathrm{PbX}_2 \ll \mathrm{SnX}_2 \ll \mathrm{GeX}_2 \ll \mathrm{SiX}_2

Correct answer

C. SiX2≪GeX2≪SnX2≪PbX2\mathrm{SiX}_2 \ll \mathrm{GeX}_2 \ll \mathrm{SnX}_2 \ll \mathrm{PbX}_2

Step-by-step solution

Due to inert pair effect, the stability of +2+2 oxidation state increases as we move down this group. ∴SiX2≪GeX2≪SnX2≪PbX2\therefore \mathrm{SiX}_2 \ll \mathrm{GeX}_2 \ll \mathrm{SnX}{ }_2 \ll \mathrm{PbX}_2 Hence, (C) is correct.
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