An octahedral complex having molecular composition Co. 5 NH ₃. Cl . SO ₄ has two isomers A and B. The solution of A gives a white precipitate with AgNO ₃ solution and the solution of B gives white precipitate with BaCl ₂ solution. The type

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An octahedral complex having molecular composition Co. 5 NH ₃. Cl . SO ₄ has two isomers A and B. The solution of A gives a white precipitate with AgNO ₃ solution and the solution of B gives white precipitate with BaCl ₂ solution. The type of isomerism exhibited by the complex is,

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Correct answer: C. Ionisation isomerism

(A) complex is [ Co ( NH ₃ )₅ ( SO ₄ ) ] Cl (B) complex is [ Co ( NH ₃ )₅ Cl ] SO ₄ Both ( A ) and ( B ) are Ionisation isomers.

An octahedral complex having molecular composition Co. 5 NH ₃. Cl . SO ₄ has two isomers A and B. The solution of A gives a white precipitate with AgNO ₃ solution and the solution of B gives white precipitate with BaCl ₂ solution. The type of isomerism exhibited by the complex is,

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