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JEE Main 202523 JanuaryMorning Shift
Exam
JEE Main
Year
2025
Date
23 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2025 · 23 January · Morning Shift · Chemistry · Coordination Compounds

The complex that shows Facial - Meridional isomerism is:

The complex that shows Facial - Meridional isomerism is:

Options

  1. A{ }_{1 .}[Co(en)2Cl2]+\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}
  2. B[Co(en)3]3+\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}
  3. C[Co(NH3)3Cl3]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]
  4. D\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+}

Correct answer

C. [Co(NH3)3Cl3]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]

Step-by-step solution

Ma3 b3\mathrm{Ma}_3 \mathrm{~b}_3 type complexes show Facial - Meridional isomerism (i) [Co(NH3)3Cl3]⇒Ma3 b3\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right] \Rightarrow \mathrm{Ma}_3 \mathrm{~b}_3 (ii) [Co(NH3)4Cl2]+⇒Ma4 b2\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]^{+} \Rightarrow \mathrm{Ma}_4 \mathrm{~b}_2 (iii) [Co(en)3]3+⇒M(AA)3\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+} \Rightarrow \mathrm{M}(\mathrm{AA})_3 (iv) [Co(en)2Cl2]+⇒M(AA)2 b2a,b,=NH3,Cl−AA=en\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+} \Rightarrow \mathrm{M}(\mathrm{AA})_2 \mathrm{~b}_2 \mathrm{a}, \mathrm{b},=\mathrm{NH}_3, \mathrm{Cl}^{-} \mathrm{AA}=\mathrm{en}
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