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JEE Main 202427 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2024 · 27 January · Evening Shift · Chemistry · Coordination Compounds

Identify from the following species in which d ^ 2 sp ^ 3...

Identify from the following species in which d2sp3{d}^{2}{sp}^{3} hybridization is shown by central atom:

Options

  1. A[Co(NH3)6]3+{\left[Co{\left({NH}_{3}\right)}_{6}\right]}^{3 +}
  2. BBrF5{BrF}_{5}
  3. C[Pt(Cl)4]2−{\left[Pt ( Cl{)}_{4}\right]}^{2 -}
  4. DSF6{SF}_{6}

Correct answer

A. [Co(NH3)6]3+{\left[Co{\left({NH}_{3}\right)}_{6}\right]}^{3 +}

Step-by-step solution

[Co(NH3)6]+3−d2sp3{\left[Co{\left({NH}_{3}\right)}_{6}\right]}^{+ 3} - {d}^{2}{sp}^{3} hybridization

In [Co(NH3)6]3+{\left[Co{\left({NH}_{3}\right)}_{6}\right]}^{3 +}, CoCo is in +3+ 3 oxidation state with the configuration 3d63{d}^{6}. In the presence of NH3{NH}_{3} a strong ligand, the 3d3d electrons pair up leaving two d-orbitals empty. Hence, the hybridization is d2sp3{d}^{2}{sp}^{3}forming an inner orbital octahedral complex. 

BrF5−sp3d2{BrF}_{5} - {sp}^{3}{d}^{2} hybridization

[PtCl4]−2−dsp2{\left[{PtCl}_{4}\right]}^{- 2} - {dsp}^{2} hybridization

SF6−sp3d2{SF}_{6} - {sp}^{3}{d}^{2} hybridization

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