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JEE Main 202315 AprilMorning Shift
Exam
JEE Main
Year
2023
Date
15 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2023 · 15 April · Morning Shift · Chemistry · Coordination Compounds

The volume (in mL ) of 0 . 1M AgNO _ 3 required for complete...

The volume (in mLmL)of0.1MAgNO3of 0 . 1M{AgNO}_{3} required for complete precipitation of chloride ions present in 20mLof0.01M20mL of 0 . 01M solution of \left[Cr{\left({H}_{2}O\right)}_{5}Cl\right]{Cl}_{2} as silver chloride is_______

Correct answer

0

Step-by-step solution

(Cr(H2O)5Cl)Cl2⟶(Cr(H2O)5Cl)+2Cl−\left(Cr{\left({H}_{2}O\right)}_{5}Cl\right){Cl}_{2} ⟶ \left(Cr{\left({H}_{2}O\right)}_{5}Cl\right) + 2{Cl}^{-}

Number of ionisable Cl−in(Cr(H2O)5Cl)Cl2{Cl}^{-} in \left(Cr{\left({H}_{2}O\right)}_{5}Cl\right){Cl}_{2} is 2.</p><p>Molarityof2 .</p><p>Molarity of{Cl}^{–}ionsions= 0 . 01 \times 2 = 0 . 02M</p><p></p><p>∴MillimolesofMillimoles of{Cl}^{–}ionsinthegivensolution</p><p>ions in the given solution</p><p>= 20 \times 0 . 02</p><p></p><p>∴MillimolesofMillimoles of{AgNO}_{3}requiredrequired= 20 \times 0 . 2</p><p></p><p>V \times 0 . 1 = 20 \times 0 . 02</p><p></p><p>V = 4mL</p></blockquote></p></blockquote>

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