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JEE Main 202330 JanuaryEvening Shift
Exam
JEE Main
Year
2023
Date
30 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2023 · 30 January · Evening Shift · Chemistry · Coordination Compounds

Match List I with List II: List I (Complexes) List II...

Match List I with List II:

List I
(Complexes)
List II
(Hybridisation)
(A) [Ni(CO)4]\left[Ni ( CO{)}_{4}\right] I sp3{sp}^{3}
(B) [Cu(NH3)4]2+{\left[Cu{\left({NH}_{3}\right)}_{4}\right]}^{2 +} II dsp2{dsp}^{2}
(C) [Fe(NH3)6]2+{\left[Fe{\left({NH}_{3}\right)}_{6}\right]}^{2 +} III sp3d2{sp}^{3}{d}^{2}
(D) [Fe(H2O)6]2+{\left[Fe{\left({H}_{2}O\right)}_{6}\right]}^{2 +} IV d2sp3{d}^{2}{sp}^{3}

Options

  1. AA – II, B – I, C – III, D – IV
  2. BA – I, B – II, C – III, D – IV
  3. CA – II, B – I, C – IV, D – III
  4. DA – I, B– II, C – IV, D – III

Correct answer

D. A – I, B– II, C – IV, D – III

Step-by-step solution

NiNi is in zero oxidation state in [Ni(CO)4][ Ni ( CO{)}_{4} ]. So, the electronic configuration of NiNi is 3d84s23{d}^{8}4{s}^{2}. As COCO is a strong ligand, it pushes all the electrons in the 3d orbital, therefore the hybridisation of [Ni(CO)4][ Ni ( CO{)}_{4} ] is sp3 and it has tetrahedral geometry. It is diamagnetic due to the absence of unpaired electrons.

[Cu(NH3)4]2+{\left[Cu{\left({NH}_{3}\right)}_{4}\right]}^{2 +} ion, oxidation state of CuCu is +2 and its valence shell electronic configuration is 3d93{d}^{9}. So, there would be a rearrangement of electrons in Cu2+{Cu}^{2 +} because of the NH3{NH}_{3} strong field ligand . And the last electron in the d-orbital would be out waiting for the N's electrons to fill up first. So, the 4 electron pairs from NN would be in one 3d, one 4s, & two 4p orbitals and in the third place of 4p orbital, the e- from 3d would take place. So, you can say the hybridisation here would be dsp2{dsp}^{2}.

[Fe(NH3)6]2+{\left[Fe{\left({NH}_{3}\right)}_{6}\right]}^{2 +} ion, oxidation state of FeFe is +2 and its valence shell electronic configuration is 3d63{d}^{6}. NH3{NH}_{3} is strong field ligand with complex. So, no pairing will be there. So, you can say the hybridisation here would be d2sp3{d}^{2}{sp}^{3}.

[Fe(H2O)6]2+{\left[Fe{\left({H}_{2}O\right)}_{6}\right]}^{2 +} ion, oxidation state of FeFe is +2 and its valence shell electronic configuration is 3d63{d}^{6}. There are 4 unpaired electrons in 3d orbital. So, you can say the hybridisation here would be sp3d2{sp}^{3}{d}^{2}.

So, correct order of matching is given in the below table:

List I
(Complexes)
List II
(Hybridisation)
[Ni(CO)4]\left[Ni ( CO{)}_{4}\right] sp3{sp}^{3}
[Cu(NH3)4]2+{\left[Cu{\left({NH}_{3}\right)}_{4}\right]}^{2 +} dsp2{dsp}^{2}
[Fe(NH3)6]2+{\left[Fe{\left({NH}_{3}\right)}_{6}\right]}^{2 +} d2sp3{d}^{2}{sp}^{3}
[Fe(H2O)6]2+{\left[Fe{\left({H}_{2}O\right)}_{6}\right]}^{2 +} sp3d2{sp}^{3}{d}^{2}
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