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Low oxidation state of metals in their complexes are common when ligands

Options

  1. Ahave good π -accepting character
  2. Bhave good σ -donor character
  3. Care havind good π -donating ability
  4. Dare havind poor σ -donating ability

Correct answer

A. have good π -accepting character

Step-by-step solution

When metal has low oxidation state, it has more electron density in d orbital. So it has more tendency to back donate electrons. Thus compound must have good π acceptor ligand. π backbonding, also called π backdonation, is when electrons move from an atomic orbital on one atom to an appropriate symmetry antibonding orbital on a π-acceptor ligand.It is especially common in the organometallic chemistry of transition metals with multi-atomic ligands such as carbon monoxide, ethylene or the nitrosonium ca

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