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Acidic ferric chloride solution on treatment with excess of potassium ferrocyanide gives a Prussian blue coloured colloidal species. It is:

Options

  1. AHFe Fe ( CN ) 6
  2. BK 5 Fe Fe ( CN ) 6 2
  3. CFe 4 Fe ( CN ) 6 3
  4. DKFe Fe ( CN ) 6

Correct answer

D. KFe Fe ( CN ) 6

Step-by-step solution

If we add ferric chloride over potassium ferrocyanide, it forms a white precipitate that will become blue. The reaction is FeCl 3 + K 4 Fe ( CN ) 6 ⟶ KFe Fe ( CN ) 6 + 3 KCl Being small quantity of ferric chloride, not all potassium is displaced.

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