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JEE Main 20262 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
2 April
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2026 · 2 April · Evening Shift · Chemistry · d and f Block Elements

Number of paramagnetic ions among the following d- and f-block...

Number of paramagnetic ions among the following d- and f-block metal ions is _______.
Mn2+,Cu2+,Zn2+,Yb2+,Sc3+,La3+,Gd3+,Lu3+,Ti4+,Ce4+Mn^{2+}, Cu^{2+}, Zn^{2+}, Yb^{2+}, Sc^{3+}, La^{3+}, Gd^{3+}, Lu^{3+}, Ti^{4+}, Ce^{4+}
(Atomic number of Mn=25,Cu=29,Zn=30,Yb=70,Sc=21,La=57,Gd=64,Lu=71,Ti=22,Ce=58Mn = 25, Cu = 29, Zn = 30, Yb = 70, Sc = 21, La = 57, Gd = 64, Lu = 71, Ti = 22, Ce = 58)

Correct answer

0

Step-by-step solution

The magnetic nature of an ion depends on the presence of unpaired electrons. Ions with at least one unpaired electron are paramagnetic, while those with all paired electrons are diamagnetic.

Let us write the electronic configurations of the given ions:

Mn2+(Z=25):[Ar]3d5Mn^{2+} (Z=25) : [Ar] 3d^5 →\rightarrow 55 unpaired electrons (Paramagnetic)
Cu2+(Z=29):[Ar]3d9Cu^{2+} (Z=29) : [Ar] 3d^9 →\rightarrow 11 unpaired electron (Paramagnetic)
Zn2+(Z=30):[Ar]3d10Zn^{2+} (Z=30) : [Ar] 3d^{10} →\rightarrow 00 unpaired electrons (Diamagnetic)
Yb2+(Z=70):[Xe]4f14Yb^{2+} (Z=70) : [Xe] 4f^{14} →\rightarrow 00 unpaired electrons (Diamagnetic)
Sc3+(Z=21):[Ar]3d0Sc^{3+} (Z=21) : [Ar] 3d^0 →\rightarrow 00 unpaired electrons (Diamagnetic)
La3+(Z=57):[Xe]4f0La^{3+} (Z=57) : [Xe] 4f^0 →\rightarrow 00 unpaired electrons (Diamagnetic)
Gd3+(Z=64):[Xe]4f7Gd^{3+} (Z=64) : [Xe] 4f^7 →\rightarrow 77 unpaired electrons (Paramagnetic)
Lu3+(Z=71):[Xe]4f14Lu^{3+} (Z=71) : [Xe] 4f^{14} →\rightarrow 00 unpaired electrons (Diamagnetic)
Ti4+(Z=22):[Ar]3d0Ti^{4+} (Z=22) : [Ar] 3d^0 →\rightarrow 00 unpaired electrons (Diamagnetic)
Ce4+(Z=58):[Xe]4f0Ce^{4+} (Z=58) : [Xe] 4f^0 →\rightarrow 00 unpaired electrons (Diamagnetic)

The paramagnetic ions are Mn2+Mn^{2+}, Cu2+Cu^{2+}, and Gd3+Gd^{3+}.

Total number of paramagnetic ions = 33.

Answer: 33
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