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JEE Main 202431 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 31 January · Evening Shift · Chemistry · d and f Block Elements

Choose the correct statements from the following A. Mn _ 2 O _ 7 is...

Choose the correct statements from the following
A. Mn2O7{Mn}_{2}{O}_{7} is an oil at room temperature B. V2O4{V}_{2}{O}_{4} reacts with acid to give VO22+{VO}_{2}^{2 +}
C. CrOCrO is a basic oxide D. V2O5{V}_{2}{O}_{5} does not react with acid
Choose the correct answer from the options given below:

Options

  1. AA, B and D only
  2. BA and C only
  3. CA, B and C only
  4. DB and C only

Correct answer

B. A and C only

Step-by-step solution

 All the metals except scandium form MO oxides, which are ionic. Mn2O7{Mn}_{2}{O}_{7} is a covalent green oil. In vanadium there is gradual change from the basic V2O3{V}_{2}{O}_{3} to less basic V2O4{V}_{2}{O}_{4} and to amphoteric V2O5{V}_{2}{O}_{5} . V2O4{V}_{2}{O}_{4} dissolves in acids to give VO2+{VO}^{2 +} salts. Similarly, V2O5{V}_{2}{O}_{5} reacts with alkalies as well as acids to give VO43−{VO}_{4}^{3 -} and VO4+{VO}_{4}^{+} respectively. The well characterised CrOCrO is basic but Cr2O3{Cr}_{2}{O}_{3} is amphoteric.

(A) Mn2O7{Mn}_{2}{O}_{7} is green oil at room temperature.

(B) V2O4{V}_{2}{O}_{4} dissolve in acids to give VO2+V{O}^{2 +} salts.

(C) CrOCrO is basic oxide.

Hence option B is the answer,

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