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JEE Main 202431 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 31 January · Morning Shift · Chemistry · d and f Block Elements

The 'Spin only’ Magnetic moment for [ Ni ( NH _ 3 ) _ 6 ] ^ 2 +...

The 'Spin only’ Magnetic moment for [Ni(NH3)6]2+[ Ni ( {NH}_{3}{)}_{6} ] {}^{2 +} is______×10–1\times {10}^{– 1} BM. (given = Atomic number of Ni:28Ni: 28)

Round off your answer to the nearest integer.The 'Spin only’ Magnetic moment for [ Ni ( NH _ 3 ) _ 6 ] ^ 2 + is______ × 10 ^ – 1 BM. (given = Atomic number of Ni:

Correct answer

0

Step-by-step solution

In the presence of ligand NH3{NH}_{3}, pairing does not occur in Ni2+{Ni}^{2 +} because pairing of electrons cannot create two vacant d-orbitals. Hence, nickel ion undergoes sp3d2{sp}^{3}{d}^{2} hybridisation and it has two unpaired electrons.

Ni2+=3d8{Ni}^{2 +} = 3{d}^{8}

The 'Spin only’ Magnetic moment for [ Ni ( NH _ 3 ) _ 6 ] ^ 2 + is______ × 10 ^ – 1 BM. (given = Atomic number of Ni:

No. of unpaired electron =2= 2

The spin only magnetic moment 

μ=n(n+2)=8=2.82BM\mu = \sqrt{n\left(n + 2\right)} = \sqrt{8} = 2 . 82BM

=28.2×10−1BM= 28 . 2 \times {10}^{- 1}BM

x=28x = 28

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