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JEE Main 202431 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 31 January · Morning Shift · Chemistry · d and f Block Elements

Identify correct statements from below: A. The chromate ion is...

Identify correct statements from below:
A. The chromate ion is square planar.
B. Dichromates are generally prepared from chromates.
C. The green manganate ion is diamagnetic.
D. Dark green coloured K2MnO4{K}_{2}{MnO}_{4} disproportionates in a neutral or acidic medium to give permanganate.
E. With increasing oxidation number of transition metal, ionic character of the oxides decreases.
Choose the correct answer from the options given below:Identify correct statements from below: A. The chromate ion is square planar. B. Dichromates are generally prepared

Options

  1. AB, C, D only
  2. BA, D, E only
  3. CA, B, C only
  4. DB, D, E only

Correct answer

D. B, D, E only

Step-by-step solution

A. CrO42−{CrO}_{4}^{2 -}: the geometry of chromate ions is tetrahedral.

Identify correct statements from below: A. The chromate ion is square planar. B. Dichromates are generally prepared

B. 2Na2CrO4+2H+→Na2Cr2O7+2Na++H2O2{Na}_{2}{CrO}_{4} + 2{H}^{+} \to {Na}_{2}{Cr}_{2}{O}_{7} + 2{Na}^{+} + {H}_{2}O

Dichromates are usually prepared from chromates and this is obtained by the combination of chromite ore with sodium/potassium carbonate in the presence of air.

C. Green manganate is paramagnetic with 11 unpaired electron.

D.

Disproportionation reaction of managanate in acidic or neutral medium is one of the preparation method for the permanaganate.
3MnO42−+4H+→2MnO4−+MnO2+2H2ODarkpurple3{MnO}_{4}^{2 -} + 4{H}^{+} \to 2{MnO}_{4}^{-} + {MnO}_{2} + 2{H}_{2}ODarkpurple
Here, Mn+6{Mn}^{+ 6} is disproportionate to Mn7+{Mn}^{7 +} and Mn4+{Mn}^{4 +}.

E. With the increasing oxidation number of transition metal, ionic character of the oxides decreases. This is because on increasing oxidation state of a cation it's size decreases and hence its polarising power increases. According to Fajan's rule smaller is the size of cation greater will be its polarising power and hence, greater will be its covalent character. So ionic character reduces.

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