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JEE Main 202430 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 30 January · Morning Shift · Chemistry · d and f Block Elements

Diamagnetic Lanthanoid ions are:

Diamagnetic Lanthanoid ions are:

Options

  1. ANd3+{Nd}^{3 +} and Eu3+{Eu}^{3 +}
  2. BLa3+{La}^{3 +} and Ce4+{Ce}^{4 +}
  3. CNd3+{Nd}^{3 +} and Ce4+{Ce}^{4 +}
  4. DLu3+{Lu}^{3 +} and Eu3+{Eu}^{3 +}

Correct answer

B. La3+{La}^{3 +} and Ce4+{Ce}^{4 +}

Step-by-step solution

Lanthanide ion with no unpaired electron is diamagnetic in nature.

Lanthanoid is also called lanthanide, which can be defined as any of the series of 1515 consecutive chemical elements in the periodic table from lanthanum to lutetium (atomic numbers 57−7157 - 71). With the elements scandium and yttrium, they make up the rare-earth metals. Lanthanides are also radioactive in nature.

Ce:[Xe]4f15d16s2;Ce4+Ce: [ Xe ] 4{f}^{1}5{d}^{1}6{s}^{2}; {Ce}^{4 +} diamagnetic

La:[Xe]4f05d16s2;La3+La: [ Xe ] 4{f}^{0}5{d}^{1}6{s}^{2}; {La}^{3 +} diamagnetic

Hence, the answer is option B.

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