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JEE Main 202430 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 30 January · Morning Shift · Chemistry · d and f Block Elements

Match List-I with List-II List I (Species) List II (Electronic...

Match List-I with List-II

  List I (Species)   List II (Electronic distribution)
A. Cr+2{Cr}^{+ 2} i. 3d83{d}^{8}
B. Mn+{Mn}^{+} ii. 3d34s13{d}^{3}4{s}^{1}
C. Ni+2{Ni}^{+ 2} iii. .3d43{d}^{4}
D. V+{V}^{+} iv. 3d54s13{d}^{5}4{s}^{1}

Choose the correct answer from the options given below:

Options

  1. A(A)-I, (B)-II, (C)-III, (D)-IV
  2. B(A)-III, (B) - IV, (C) - I, (D)-II
  3. C(A)-IV, (B)-III, (C)-I, (D)-II
  4. D(A)-II, (B)-I, (C)-IV, (D)-III

Correct answer

B. (A)-III, (B) - IV, (C) - I, (D)-II

Step-by-step solution

Electrons must be removed from the outermost orbital to form an ion.

The electronic configurations of the elements are as follows,

Cr24→[Ar]3d54s1;Cr2+→[Ar]3d4Cr 24 \to [ Ar ] 3{d}^{5}4{s}^{1}; {Cr}^{2 +} \to [ Ar ] 3{d}^{4}

Mn25→[Ar]3d54s2;Mn+→[Ar]3d54s1Mn 25 \to [ Ar ] 3{d}^{5}4{s}^{2}; {Mn}^{+} \to [ Ar ] 3{d}^{5}4{s}^{1}

Ni28→[Ar]3d84s2;Ni2+→[Ar]3d8Ni 28 \to [ Ar ] 3{d}^{8}4{s}^{2}; {Ni}^{2 +} \to [ Ar ] 3{d}^{8}

23V→[Ar]3d34s2;V+→[Ar]3d34s123 V \to [ Ar ] 3{d}^{3}4{s}^{2}; {V}^{+} \to [ Ar ] 3{d}^{3}4{s}^{1}

Hence option B is the answer.

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