JEE Main202427 Jan 2024Evening ShiftChemistryd and f Block ElementsActual
Given below are two statements: Statement (I) : In the Lanthanoids, the formation of Ce + 4 is favoured by its noble gas configuration. Statement (II) : Ce + 4 is a strong oxidant reverting to the common + 3 state. In the light of the above statements, choose the most appropriate answer from the options given below:
Options
- AStatement I is false but Statement II is true
- BBoth Statement I and Statement II are true
- CStatement I is true but Statement II is false
- DBoth Statement I and Statement II are false
Correct answer
B. Both Statement I and Statement II are true
Step-by-step solution
Statement (1) is true, Ce + 4 has noble gas electronic configuration. Statement (2) is also true. The formation of Ce 4 + is favoured by its noble gas configuration, but it is a strong oxidant reverting to the common + 3 state. The E o value for Ce 4 + / Ce 3 + is + 1 . 74 V which suggests that it can oxidise water. However, the reaction rate is very slow and hence Ce ( IV ) is a good analytical reagent. An oxidising agent is a substance that oxidises other substances involved in the reaction by gaining or acceptin