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JEE Main 202427 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 27 January · Evening Shift · Chemistry · d and f Block Elements

Given below are two statements: Statement (I) : In the Lanthanoids,...

Given below are two statements:
Statement (I) : In the Lanthanoids, the formation of Ce+4{Ce}^{+ 4} is favoured by its noble gas configuration.
Statement (II) : Ce+4{Ce}^{+ 4} is a strong oxidant reverting to the common +3+ 3 state.
In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. AStatement I is false but Statement II is true
  2. BBoth Statement I and Statement II are true
  3. CStatement I is true but Statement II is false
  4. DBoth Statement I and Statement II are false

Correct answer

B. Both Statement I and Statement II are true

Step-by-step solution

Statement (1) is true, Ce+4{Ce}^{+ 4} has noble gas electronic configuration.
Statement (2) is also true. The formation of Ce4+{Ce}^{4 +} is favoured by its noble gas configuration, but it is a strong oxidant reverting to the common +3+ 3 state. The Eo{E}^{o} value forCe4+/Ce3+is+1.74V{Ce}^{4 +} / {Ce}^{3 +}is + 1 . 74Vwhich suggests that it can oxidise water. However, the reaction rate is very slow and hence Ce(IV)Ce ( IV ) is a good analytical reagent.
An oxidising agent is a substance that oxidises other substances involved in the reaction by gaining or accepting electrons from them. It is also referred to as an oxidiser or oxidant.

Hence, both the statements are correct.

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