Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main202427 Jan 2024Evening ShiftChemistryd and f Block ElementsActual

Given below are two statements: Statement (I) : In the Lanthanoids, the formation of Ce + 4 is favoured by its noble gas configuration. Statement (II) : Ce + 4 is a strong oxidant reverting to the common + 3 state. In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. AStatement I is false but Statement II is true
  2. BBoth Statement I and Statement II are true
  3. CStatement I is true but Statement II is false
  4. DBoth Statement I and Statement II are false

Correct answer

B. Both Statement I and Statement II are true

Step-by-step solution

Statement (1) is true, Ce + 4 has noble gas electronic configuration. Statement (2) is also true. The formation of Ce 4 + is favoured by its noble gas configuration, but it is a strong oxidant reverting to the common + 3 state. The E o value for Ce 4 + / Ce 3 + is + 1 . 74 V which suggests that it can oxidise water. However, the reaction rate is very slow and hence Ce ( IV ) is a good analytical reagent. An oxidising agent is a substance that oxidises other substances involved in the reaction by gaining or acceptin

Practice d and f Block Elements on Quantrex Academy →

More from d and f Block Elements

Given below are two statements: Statement I: The number of pairs among [ Ti ⁴⁺, V ²⁺] , [ V ²⁺, Mn ²⁺] , [ Mn ²⁺, Fe ³⁺] and [ V ²⁺, Cr ²⁺] in which both ions are coloured is 3 . S 2026Given below are two statements for catalytic properties of transition metals. Statement I: First row transition metals which act as catalyst utilise their 3d electrons only for 2026The correct order of first ( _i H₁) and second ( _i H₂) ionisation enthalpy values of Cr and Mn are : A. _i H₁ : Cr > Mn B. _i H₂ : Cr > Mn C. _i H₁ : Mn > Cr D. _i H₂ : Mn > Cr Ch 2026The correct statements among the following are. A. Basic vanadium oxide is used in the manufacture of H ₂ SO ₄ . B. The spin-only magnetic moment value of the transition metal hali 2026Given below are two statements : Statement I: Presence of large number of unpaired electrons in transition metal atoms results in higher enthalpies of their atomisation. Statement 2026A paper dipped in a dil. H₂SO₄ solution of ' X ' upon treatment with SO₂ gas turns into green. The compound ' X ' is : 2026Which of the following is NOT a physical or chemical characteristics of interstitial compounds? 2026Pairs of elements with the same number of electrons in their respective 4f orbital are [Atomic number. Eu-63, Gd-64, Dy-66, Ho-67, Tm-69, Yb-70, Lu-71, Hf-72] A. (Eu and Gd) B. (Dy 2026 Full d and f Block Elements list All JEE Main PYQs