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JEE Main 202427 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Morning Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2024 · 27 January · Morning Shift · Chemistry · d and f Block Elements

NaCl reacts with conc. H _ 2 SO _ 4 and K _ 2 Cr _ 2 O _ 7 to give...

NaClNaCl reacts with conc. H2SO4{H}_{2}{SO}_{4} and K2Cr2O7{K}_{2}{Cr}_{2}{O}_{7} to give reddish fumes (B), which react with NaOHNaOH to give yellow solution (C). (B) and (C) respectively are ;

Options

  1. ACrO2Cl2,Na2CrO4{CrO}_{2}{Cl}_{2}, {Na}_{2}{CrO}_{4}
  2. BNa2CrO4,CrO2Cl2{Na}_{2}{CrO}_{4}, {CrO}_{2}{Cl}_{2}
  3. CCrO2Cl2,KHSO4{CrO}_{2}{Cl}_{2}, {KHSO}_{4}
  4. DCrO2Cl2,Na2Cr2O7{CrO}_{2}{Cl}_{2}, {Na}_{2}{Cr}_{2}{O}_{7}

Correct answer

A. CrO2Cl2,Na2CrO4{CrO}_{2}{Cl}_{2}, {Na}_{2}{CrO}_{4}

Step-by-step solution

Chromyl chloride (B) is produced when a chloride ion reacts with conc.H2SO4{H}_{2}{SO}_{4} and K2Cr2O7{K}_{2}{Cr}_{2}{O}_{7}.
Passing the chromyl chloride gas through NaOHNaOH turns the solution yellow. This is due to the formation of Na2CrO4{Na}_{2}{CrO}_{4} (C).

The reaction is as follows,

NaCl+conc.H2SO4+K2Cr2O7→CrO2Cl2(B)(Reddishbrown)+KHSO4+NaHSO4+H2ONaCl + conc . {H}_{2}{SO}_{4} + {K}_{2}{Cr}_{2}{O}_{7} \to \mathop{{CrO}_{2}{Cl}_{2}}_{\mathop{( B )}_{( Reddishbrown )}} + {KHSO}_{4} + {NaHSO}_{4} + {H}_{2}O

CrO2Cl2+NaOH→Na2CrO4(C)YellowColour+NaCl+H2O{CrO}_{2}{Cl}_{2} + NaOH \to \mathop{{Na}_{2}{CrO}_{4}}_{\mathop{( C )}_{YellowColour}} + NaCl + {H}_{2}O

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