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99 Percentile Qs Bank for JEE MainChemistryClassification of Elements and Periodicity in Properties

Within each pair of elements F and C l , S and S e , and Li   and Na , respectively, the elements that release more energy upon an electron gain are

Options

  1. AC l , S e and N a
  2. BC l , S and L i
  3. CF , S and L i
  4. DF , S e and N a

Correct answer

B. C l , S and L i

Step-by-step solution

(i) Electron affinity of second period p -block element is less than third period p -block element due to small size of second period p -block element, due to small size electron density is more and upcoming electron face extra repulsion, so energy release is less. Hence, EA order: F < Cl . (ii) Down the group electron affinity decreases due to size increases. EA order: S > Se   Li > Na .

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