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JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main · Chemistry · p Block Elements (Group 13 & 14)

In which of the following reactions, hydrogen is liberated? (i)...

In which of the following reactions, hydrogen is liberated? (i) Al(s)+HCl(aq)⟶\mathrm{Al}(s)+\mathrm{HCl}(a q) \longrightarrow (ii) Al(s)+NaOH(aq)⟶\mathrm{Al}(s)+\mathrm{NaOH}(a q) \longrightarrow (iii) NaBH4+\mathrm{NaBH}_4+\mathrm{I}2⟶_2 \longrightarrow

Options

  1. Ai, ii
  2. Bii, iii
  3. Ci, iii
  4. Di, ii, iii

Correct answer

D. i, ii, iii

Step-by-step solution

(i) 2Al(s)+6HCl(aq)⟶2AlCl3(aq)+3H22 \mathrm{Al}(s)+6 \mathrm{HCl}(a q) \longrightarrow 2 \mathrm{AlCl}_3(a q)+3 \mathrm{H}_2 (ii) 2Al(s)+2NaOH(aq)⟶2Na[Al(OH)4]+3H2 Sodium tetrahydroxo  aluminate (III) \begin{aligned}2 \mathrm{Al}(s)+2 \mathrm{NaOH}(a q) \longrightarrow & \\ & 2 \mathrm{Na}\left[\mathrm{Al}(\mathrm{OH})_4\right]+3 \mathrm{H}_2 \\ & \begin{array}{l} \text { Sodium tetrahydroxo }\\ \text { aluminate (III) } \end{array} \end{aligned}(iii) \begin{aligned} \mathrm{NaBH}}_{4}+\mathrm{I}_2 \longrightarrow & \mathrm{BH}_3+\mathrm{NaI}+\mathrm{HI} \\ & \downarrow\left(\mathrm{NaBH}_4\right) \\ & 2 \mathrm{BH}_3+2 \mathrm{NaI}+\mathrm{H}_2 \end{aligned}
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