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JEE Main
Exam
JEE Main
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main · Chemistry · p Block Elements (Group 13 & 14)

Consider the following statements: I. In diamond, each carbon atom...

Consider the following statements: I. In diamond, each carbon atom is sp3s p^3-hybridised. II. Graphite has planar hexagonal layers of carbon atoms. III. Silicones being surrounded by non-polar alkyl groups are water repelling in nature IV. The order of catenation in group 14 elements is Si>C>Sn>Ge>Pb\mathrm{Si}>\mathrm{C}>\mathrm{Sn}>\mathrm{Ge}>\mathrm{Pb}. The correct statements are

Options

  1. AI, II, III
  2. BII, III, IV
  3. CI, II, IV
  4. DI, III, IV

Correct answer

A. I, II, III

Step-by-step solution

(I, II) In diamond, hybridisation of carbon is sp3s p^3 and graphite has planar hexagonal layer of C\mathrm{C}-atoms. The hybridisation of each C\mathrm{C}-atom in graphite is sp2s p^2. (III) Silicones are organo-silicon polymers formed from inorganic and organic monomer having chemical formula \left(R_2 \mathrm{SiO}\right)_n,duetonon−polaralkylgroup,siliconesarewaterrepellinginnature.(IV)Thecatenationtendencyingroup14elementsdecreasesduetodecreaseinelementbondstrength.Thus,thecorrectorderis, due to non-polar alkyl group, silicones are water repelling in nature. (IV) The catenation tendency in group 14 elements decreases due to decrease in element bond strength. Thus, the correct order is\mathrm{C}>>>>\mathrm{Si}>>\mathrm{Ge} \approx \mathrm{Sn}Hence,statement(IV)isincorrect.Thus,option(a)iscorrect.Hence, statement (IV) is incorrect. Thus, option (a) is correct.
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