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99 Percentile Qs Bank for JEE MainChemistryp Block Elements (Group 13 & 14)

Identify the correct statements from the following : I. Ga ₂ O ₃ is an amphoteric oxide. II. The dimer of aluminium chloride has three Al - Cl - Al bridge bonds. III. Boron is very hard refractory solid of high melting temperature.

Options

  1. AI, II only
  2. BI, III only
  3. CII, III only
  4. DI, II, III

Correct answer

B. I, III only

Step-by-step solution

(I) Ga ₂ O ₃ is an amphoteric oxide is the correct statement as it reacts with acid and base both, as shown below : Reaction with an acid Ga ₂ O ₃+6 HCl 2 GaCl ₃+3 H ₂ O Reaction with a base Ga ₂ O ₃+2 NaOH 2 NaGaO ₂+ H ₂ O (II) The dimer of aluminium chloride has three Al - Cl - Al bridge bond is not the correct statement as structure of Al ₂ Cl ₆ is as follows: (III) Boron is very hard refractory solid of high melting temperature is the correct statement as its melting point is 2349 ~K and is used as refractory s

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