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JEE Main 202431 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2024 · 31 January · Morning Shift · Chemistry · p Block Elements (Group 13 & 14)

Consider the oxides of group 14 elements Si O _ 2 , Ge O _ 2 , Sn O...

Consider the oxides of group 1414 elements SiO2,GeO2,SnO2,PbO2,COSi{O}_{2}, Ge{O}_{2}, Sn{O}_{2}, Pb{O}_{2}, CO and GeOGeO. The amphoteric oxides are

Options

  1. AGeO,GeO2GeO, {GeO}_{2}
  2. BSiO2,GeO2{SiO}_{2}, {GeO}_{2}
  3. CSnO2,PbO2{SnO}_{2}, {PbO}_{2}
  4. DSnO2,CO{SnO}_{2}, CO

Correct answer

C. SnO2,PbO2{SnO}_{2}, {PbO}_{2}

Step-by-step solution

All members of group 14 when heated in oxygen form oxides. There are mainly two types of oxides, i.e., monoxide and dioxide of formula MOMO and MO2{MO}_{2} respectively. SiOSiO only exists at high temperature. Oxides in higher oxidation states of elements are generally more acidic than those in lower oxidation states. The dioxides CO2,SiO2{CO}_{2}, {SiO}_{2} and GeO2{GeO}_{2} are acidic, whereas SnO2{SnO}_{2} and PbO2{PbO}_{2} are amphoteric in nature. Amongst monoxides, COCO is neutral.

Hence option C is the answer.

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