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JEE Main 202429 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
29 January
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2024 · 29 January · Morning Shift · Chemistry · p Block Elements (Group 13 & 14)

Given below are two statements : Statement I : The...

Given below are two statements :

Statement I : The electronegativity of group 1414 elements from SiSi to PbPb gradually decreases.

Statement II : Group 1414 contains non-metallic, metallic, as well as metalloid elements.

In the light of the above statements, choose the most appropriate from the options given below :

Options

  1. AStatement I is false but Statement II is true
  2. BStatement I is true but Statement II is false
  3. CBoth Statement I and Statement II are true
  4. DBoth Statement I and Statement II are false

Correct answer

A. Statement I is false but Statement II is true

Step-by-step solution

Gr−14ENGr - 14EN

C2.5C2 . 5

Si1.8Si1 . 8

Ge1.8Ge1 . 8

Sn1.8Sn1 . 8

Pb1.9Pb1 . 9

The electronegativity values for elements from SiSi to PbPb are almost same. So Statement I is false.

  1. Among them, Carbon and silicon are non-metals.
  2. Germanium is metalloid in nature
  3. Tin and lead are metal.

Reason for different metallic characteristics

  1. The metallic character increases down the group from carbon to lead as nonmetal to metal.
  2. The metallic character increases because the atomic size increases from Carbon to Lead.
  3. As size increases, the ionization potential decreases down the group.
  4. A decrease in ionization potential lead to an increase in the electropositive character of the element.

Hence, the metallic character increases down the group in group−14- 14 as the ionization potential decreases to make it easier to lose an electron and increase the metallic character.

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