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JEE Main 202229 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
29 July
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2022 · 29 July · Evening Shift · Chemistry · p Block Elements (Group 13 & 14)

When borax is heated with CoO on a platinum loop, blue coloured...

When borax is heated with CoOCoO on a platinum loop, blue coloured bead formed is largely due to

Options

  1. AB2O3{B}_{2}{O}_{3}
  2. BCo{\left({BO}_{2}\right)}_{2}
  3. CCoB4O7{CoB}_{4}{O}_{7}
  4. DCo[B4O5(OH)4]Co\left[{B}_{4}{O}_{5}{\left(OH\right)}_{4}\right]

Correct answer

B. Co{\left({BO}_{2}\right)}_{2}

Step-by-step solution

On heating, borax loses its water of crystallisation and decomposes to give sodium metaborate and boric anhydride

Na2B4O7⋅10H2O⟶ΔNa2B4O7+10H2O{Na}_{2}{B}_{4}{O}_{7} \cdot 10{H}_{2}O\overset{\Delta}{⟶}{Na}_{2}{B}_{4}{O}_{7} + 10{H}_{2}O

Na2B4O7⟶Δ2NaBO2{Na}_{2}{B}_{4}{O}_{7}\overset{\Delta}{⟶}2{NaBO}_{2} (sodium meta borate) +B2O3+ {B}_{2}{O}_{3}

On treatment with metal salt, boric anhydride forms metaborate of the metal which gives different colours in oxidising and reducing flame. For example, in the case of copper sulphate, following reactions occur

B2O3+CoO→Co(BO2)2{B}_{2}{O}_{3} + CoO \to Co{\left({BO}_{2}\right)}_{2}

(cobalt \left(II\right) metaborate)
Blue Bead

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