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JEE Main 202227 JulyEvening Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Evening Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2022 · 27 July · Evening Shift · Chemistry · p Block Elements (Group 13 & 14)

Given below are two statements: one is labelled as Assertion A and...

Given below are two statements: one is labelled as Assertion AA and the other is labelled as Reason RR

Assertion AA: Boron is unable to form BF63−{BF}_{6}^{3 -}

Reason RR: Size of BB is very small.

In the light of the above statements, choose the correct answer from the options given below

Options

  1. ABoth AA and RR are true and RR is the correct explanation of AA
  2. BBoth AA and RR are true but RR is not the correct explanation of AA
  3. CAA is true but RR is false
  4. DAA is false but RR is true

Correct answer

B. Both AA and RR are true but RR is not the correct explanation of AA

Step-by-step solution

Due to non-availability of d orbitals, boron is unable to expand its octet. Therefore, the maximum covalence of boron cannot exceed 44.

Boron is the first element from top in group 1313 and the atomic size increases down the group. Therefore, boron is smallest in size.

Assertion AA: True

Reason RR: True but not correct explanation.

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