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JEE Main 202127 AugustMorning Shift
Exam
JEE Main
Year
2021
Date
27 August
Shift
Morning Shift
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Main 2021 · 27 August · Morning Shift · Chemistry · p Block Elements (Group 13 & 14)

In which one of the following molecules strongest back donation of...

In which one of the following molecules strongest back donation of an electron pair from halide to boron is expected?In which one of the following molecules strongest back donation of an electron pair from halide to boron is expected?

Options

  1. ABI3{BI}_{3}
  2. BBBr3{BBr}_{3}
  3. CBCl3{BCl}_{3}
  4. DBF3{BF}_{3}

Correct answer

D. BF3{BF}_{3}

Step-by-step solution

In which one of the following molecules strongest back donation of an electron pair from halide to boron is expected?

Due to small size atom show strongest back bonding in BF3.<br/>Incaseof{BF}_{3} .<br />In case of{BF}_{3}((2P - 2Pbackbonding)whileinback bonding) while in{BCl}_{3} ( 2P - 3P ) , {BBr}_{3} ( 2P - 4P ) and {BI}_{3} ( 2P - 5P )back bonding. So extent of back bonding is maximum in \left(2P - 2P\right)

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