Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
Most Important Selected Qs for JEE AdvancedChemistryCoordination Compounds

In the crystal field of the complex [ Fe ( Cl )( CN )₄ ( O ₂ ) ]⁴⁻ the electronic configuration of metal is found to be t _ 2 ~g ^6, e _ g ^0 then which of the following is true about this complex ion :

Options

  1. AIt is a paramagnetic complex
  2. BO - O bond length will be less than found in O ₂ molecule
  3. CIts IUPAC name will be chlorotetracyanosuperoxidoferrate (II) ion
  4. DIt is a diamagnetic complex

Correct answer

C. Its IUPAC name will be chlorotetracyanosuperoxidoferrate (II) ion

Step-by-step solution

The given complex is actually hence Fe ( II ) is t _ 2 ~g ^6, e _ g ^0 due to effect of strong ligands but it is paramagnetic due to O ₂ ⁻¹ ligand.

Practice Coordination Compounds on Quantrex Academy →

More from Coordination Compounds

Reaction of PtF ₆ with oxygen ( O ₂ ) gas results in the formation of an ionic compound, X ^+ Y ^- . Correct statement(s) is(are) 2026The total number of all possible isomers for the square planar complex with formula K [ M(NCS)(NO ₂ )(gly) ] is ____. ( M = metal ion and gly = NH ₂ CH ₂ COO ^- ) 2026Consider that the coordinating atoms of the ligands in cis -[Co(NH₃ )₄ Cl₂ ]Cl and mer -[Co(NH₃ )₃ Cl₃ ] octahedral complexes are at the vertices of an octahedron. The sum of total 2026Number of paramagnetic complexes among the following is ________. [ MnBr ₄]²⁻ , [ NiCl ₄]²⁻ , [ Ni(CN) ₄]²⁻ , [ Ni(CO) ₄] , [ CoF ₆]³⁻ , [ Fe(CN) ₆]⁴⁻ , [ Mn(CN) ₆]³⁻ , [ Ti(CN) ₆] 2026Which of the following sequences of hybridisation, geometry and magnetic nature are correct for the given coordination compounds ? A. [ NiCl ₄]²⁻- sp ^3 , tetrahedral, paramagnetic 2026An excess of AgNO₃ is added to 100 mL of a 0.05 M solution of tetraaquadichloridochromium (III) chloride. The number of moles of AgCl precipitated will be __________ 10⁻³ . (Neares 2026Match the List-I with List-II List-I Electronic configuration of tetrahedral metal ion List-II Crystal Field Stabilization Energy ( _t ) A. d^2 I. -0.6 B. d^4 II. -0.8 C. d^6 III. 2026Which of the following are true about the energy of the given d-orbitals of a tetrahedral complex? A. d_ xy = d_ xz > d_ x^2-y^2 B. d_ xy = d_ yz > d_ z^2 C. d_ x^2-y^2 > d_ z^2 > 2026 Full Coordination Compounds list All Most Important Selected Qs for JEE Advanced PYQs