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JEE Main 202429 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
29 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Practical Chemistry

JEE Main 2024 · 29 January · Evening Shift · Chemistry · Practical Chemistry

On passing a gas, ' X ', through Nessler's reagent, a brown...

On passing a gas, 'XX', through Nessler's reagent, a brown precipitate is obtained. The gas 'XX ' is

Options

  1. AH2S{H}_{2}S
  2. BCO2{CO}_{2}
  3. CNH3{NH}_{3}
  4. DCl2{Cl}_{2}

Correct answer

C. NH3{NH}_{3}

Step-by-step solution

Nessler's reagent is an aqueous solution of potassium iodide, mercuric chloride, and potassium hydroxide. Its chemical formula is K2HgI4{K}_{2}{HgI}_{4}. It is used to detect the presence of ammonia. It turns into a pale brown colour in the presence of ammonia.

Nessler’s Reagent Reaction:

2K2HgI4⏟Nessler′sreagent+NH3+3KOH→HgO.Hg(NH2)I⏟IodideofMillon′sbase(brownprecipitate)+7KI+2H2O2\mathop{\mathop{{K}_{2}{HgI}_{4}}_{⏟}}_{Nessler ' sreagent} + {NH}_{3} + 3KOH\overset{}{\to}\mathop{\mathop{HgO . Hg\left({NH}_{2}\right)I}_{⏟}}_{IodideofMillon ' sbase\left(brownprecipitate\right)} + 7KI + 2{H}_{2}O

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