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JEE Main 202224 JuneMorning Shift
Exam
JEE Main
Year
2022
Date
24 June
Shift
Morning Shift
Subject
Chemistry
Chapter
Practical Chemistry

JEE Main 2022 · 24 June · Morning Shift · Chemistry · Practical Chemistry

During the qualitative analysis of salt with cation y ^ 2 + ,...

During the qualitative analysis of salt with cation y2+{y}^{2 +}, addition of a reagent (X)\left(X\right) to alkaline solution of the salt gives a bright red precipitate. The reagent (X)\left(X\right) and the cation (y2+)\left({y}^{2 +}\right) present respectively are :

Options

  1. ADimethylglyoxime and Ni2+{Ni}^{2 +}
  2. BDimethylglyoxime and Co2+{Co}^{2 +}
  3. CNessler's reagent and Hg2+{Hg}^{2 +}
  4. DNessler's reagent and Ni2+{Ni}^{2 +}

Correct answer

A. Dimethylglyoxime and Ni2+{Ni}^{2 +}

Step-by-step solution

During the qualitative analysis of salt with cation Ni2+{Ni}^{2 +}, addition of a reagent DimethylglyoximeDimethylglyoxime to alkaline solution of the salt gives a bright red precipitate according to the following reaction. So, The reagent (X)\left(X\right) and the cation (y2+)\left({y}^{2 +}\right) respectively are Dimethylglyoxime and Ni2+{Ni}^{2 +}

Ni2++dmg→AmmonicalSolution[Ni(dmg)2]Redcolur↓{Ni}^{2 +} + dmg\overset{AmmonicalSolution}{\to}\mathop{\left[Ni{\left(dmg\right)}_{2}\right]}_{Redcolur} ↓,

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