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JEE Main 20231 FebruaryMorning Shift
Exam
JEE Main
Year
2023
Date
1 February
Shift
Morning Shift
Subject
Chemistry
Chapter
Solid State

JEE Main 2023 · 1 February · Morning Shift · Chemistry · Solid State

Which of the following represents the lattice structure of A _ 0 ....

Which of the following represents the lattice structure of A0.95O{A}_{0 . 95}O containing A2+,A3+{A}^{2 +} , {A}^{3 +} and O2–{O}^{2 –} ions?

Which of the following represents the lattice structure of A _ 0 . 95 O containing A ^ 2 + , A ^ 3 + and O ^ 2 – ions?

A.
Which of the following represents the lattice structure of A _ 0 . 95 O containing A ^ 2 + , A ^ 3 + and O ^ 2 – ions?

B.
Which of the following represents the lattice structure of A _ 0 . 95 O containing A ^ 2 + , A ^ 3 + and O ^ 2 – ions?

C.
Which of the following represents the lattice structure of A _ 0 . 95 O containing A ^ 2 + , A ^ 3 + and O ^ 2 – ions?

Options

  1. AB and C only
  2. BB only
  3. CA and B only
  4. DA only

Correct answer

D. A only

Step-by-step solution

Applying the electrical neutrality principle in metal deficiency defect.

One A2+ismissingthentwo{A}^{2 +} is missing then two{A}^{2 +}ionsareconvertedintoions are converted into{A}^{3 +}ionsoion so0 . 05{A}^{2 +}ionaremissingand(0.05×2)A2+ion are missing and \left(0 . 05 \times 2\right) {A}^{2 +} ion are converted in A3+{A}^{3 +} ion so for each O2−{O}^{2 -} ion total A2+{A}^{2 +} ion 0 . 85 and A3+{\text{A}}^{3 +} ion is 0.10 . 1.

Hence, A satisfies the condition.

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