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JEE Main 201411 AprilOnline
Exam
JEE Main
Year
2014
Date
11 April
Mode
Online
Subject
Chemistry
Chapter
Solid State

JEE Main 2014 · 11 April · Online · Chemistry · Solid State

The appearance of colour in solid alkali metal halides is generally...

The appearance of colour in solid alkali metal halides is generally due to:

Options

  1. ASchottky defect
  2. BFrenkel defect
  3. CInterstitial position
  4. DF-centres

Correct answer

D. F-centres

Step-by-step solution

The appearance of colour in alkali metal halides is generally due to F-centres. F centers in NaCl\mathrm{NaCl} produce a band of optical absorption towards the blue end of visible spectrum, thus the colour appears yellow under transmitted light. On the other hand, KCl\mathrm{KCl} with F\mathrm{F}-centers appears magenta, and KBr\mathrm{KBr} appears blue.
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