JEE Main 201219 MayOnline
- Exam
- JEE Main
- Year
- 2012
- Date
- 19 May
- Mode
- Online
- Subject
- Chemistry
- Chapter
- Solid State
JEE Main 2012 · 19 May · Online · Chemistry · Solid State
Ammonium chloride crystallizes in a body centred cubic lattice with...
Ammonium chloride crystallizes in a body centred cubic lattice with edge length of unit cell of 390 . If the size of chloride ion is , the size of ammonium ion would be
Options
- A
- B
- C
- D
Correct answer
B.
Step-by-step solution
For bcc structure
\begin{aligned}& r_{\mathrm{NH}_4}^{+}}^{+}+r_{\mathrm{Cl}^{-}}^{-}=\frac{\sqrt{3}}{2} a \\
& r_{\mathrm{NH}_4}^{+}}^{+}+180=\frac{\sqrt{3}}{2} \times390
\end{aligned}
\mathrm{r}_{\mathrm{NH}_4^{+}}^{+}=338 \mathrm{pm}-180 \mathrm{pm}=158 \mathrm{pm}$