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JEE Main 20252 AprilMorning Shift
Exam
JEE Main
Year
2025
Date
2 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2025 · 2 April · Morning Shift · Chemistry · Some Basic Concepts of Chemistry

On complete combustion 1.0 g of an organic compound (X) gave 1.46 g...

On complete combustion 1.0 g of an organic compound (X) gave 1.46 g of (\mathrm{CO}}_{2}) and 0.567 g of (\mathrm{H}}_{2} O\mathrm{O}). The empirical formula mass of compound ((X)\mathrm{X})) is ________ g.
(Given molar mass in (gmol−1C\mathrm{g} \mathrm{mol}^{-1} \mathrm{C}: 12, H\mathrm{H}: 1, O\mathrm{O}: 16))

Options

  1. A30
  2. B45
  3. C60
  4. D15

Correct answer

A. 30

Step-by-step solution

Moles of ' C ' (=nCO2=1.4644=\mathrm{n}_{\mathrm{CO}_2}=\frac{1.46}{44}=0.033)
Moles of ' C ' (=WC=\mathrm{W}_{\mathrm{C}}=0.033 ×\times12)
Moles of 'H' (=2 ×nH2O=\times \mathrm{n}_{\mathrm{H}_2 \mathrm{O}}=2 ×0.56718=\times \frac{0.567}{18}=0.063)
Mass of ' H ' =0.0063=0.0063
Mass of Oxygen ((\mathrm{O})=1−(Wc+WH))(=1−(0.033×1-\left(\mathrm{W}_{\mathrm{c}}+\mathrm{W}_{\mathrm{H}}\right)) (=1-(0.033 \times12+0.063 ×\times1)=0.541 gm)<br/>Molesof′O′(=0.54116=\mathrm{gm})<br />Moles of ' O ' (=\frac{0.541}{16}=0.033)
Empirical formula (=\mathrm{CH}}_{2} \mathrm{O})
Empirical formula mass =30=30.
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