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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Some Basic Concepts of Chemistry

250g solution of D -glucose in water contains 10 . 8 % of carbon by...

250g250g solution of DD-glucose in water contains 10.810 . 8 % of carbon by weight. The molality of the solution is nearest to (Given: Atomic Weights are H=1u;C=12u;O=16uH = 1u; C = 12u; O = 16u)

Options

  1. A1.031 . 03
  2. B2.062 . 06
  3. C3.093 . 09
  4. D5.405 . 40

Correct answer

B. 2.062 . 06

Step-by-step solution

C6H12O6→Glucose{C}_{6}{H}_{12}{O}_{6} \to Glucose

Given: % C = 10 . 8 = \dfrac{mass of C}{massof solution} \times 100

10.8×250100=\dfrac{10 . 8 \times 250}{100} = mass of C⇒C ⇒ Mass of C=27gmC = 27gm

massofCmassofglucose=72180massofglucose=27×18072\dfrac{mass of C}{massofglucose} = \dfrac{72}{180}massofglucose = 27 \times \dfrac{180}{72}

∴∴ mass of glucose =67.5gm= 67 . 5gm

∴∴ moles of glucose =67.5180=0.375= \dfrac{67 . 5}{180} = 0 . 375 moles

Mass of solvent =250−67.5gm=182.5gm= 250 - 67 . 5gm = 182 . 5gm

∴∴ Molality =molesofsolutemassofsolvent(kg)=0.3750.1825=2.055≈2.06= \dfrac{molesofsolute}{massofsolvent ( kg )} = \dfrac{0 . 375}{0 . 1825} = 2 . 055 \approx 2 . 06

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