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JEE Main 20207 JanuaryEvening Shift
Exam
JEE Main
Year
2020
Date
7 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Main 2020 · 7 January · Evening Shift · Chemistry · Some Basic Concepts of Chemistry

The ammonia ( NH _ 3 ) released on quantitative reaction of 0.6g...

The ammonia (NH3)\left({NH}_{3}\right) released on quantitative reaction of 0.6g0.6g urea \left({NH}_{2}CON{H}_{2}\right)withsodiumhydroxide(NaOH)with sodium hydroxide \left(NaOH\right) can be neutralized by

Options

  1. A200ml200ml of 0.4NHCl0.4NHCl
  2. B200ml200ml of 0.2NHCl0.2NHCl
  3. C100ml100ml of 0.2NHCl0.2NHCl
  4. D100ml100ml of 0.1NHCl0.1NHCl

Correct answer

C. 100ml100ml of 0.2NHCl0.2NHCl

Step-by-step solution

NH2CONH2+2NaOH→2NH3+Na2CO3{NH}_{2}{CONH}_{2} + 2NaOH \to 2{NH}_{3} + {Na}_{2}{CO}_{3}

By, stoichiometry, 1mol1mol of urea gives 2mol2mol NH3{NH}_{3}

Moles of urea ==0.6gm60gm/mol=0.01mol= \dfrac{0 . 6gm}{60gm / mol} = 0 . 01mol

So, 0.010 . 01 mole urea produce 0.020 . 02 mole NH3{NH}_{3}

To neutralize ammonia HClHCl is required

NH3+HCl→NH4Cl{NH}_{3} + HCl \to {NH}_{4}Cl

By equation, it is clear that 1mol1mol of ammonia is neutralized by 1mol of HClHCl.

So, 0.02mol0 . 02mol of ammonia neutralized by 0.02mol0 . 02mol of HClHCl

∴MoleofHCl=0.02mole∴ MoleofHCl = 0.02mole

EquivalentofHCl=normality×volume=0.2N×100mL=0.02equivalentEquivalentofHCl = normality \times volume = 0 . 2N \times 100mL = 0 . 02equivalent

As nn-factor of HClHCl is 11, so numberofequivalents=numberofmoles=0.02molesnumberofequivalents = numberofmoles = 0 . 02moles

Hence, option 33 is correct.

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