Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202331 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
31 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2023 · 31 January · Morning Shift · Chemistry · Thermodynamics (C)

The enthalpy change for the conversion of (1)/(2) Cl _ 2 (g) to Cl...

The enthalpy change for the conversion of 12Cl2\dfrac{1}{2}{Cl}_{2} (g) to Cl−(aq){Cl}^{-} ( aq ) is (−)( - )
kJmol−1{kJmol}^{- 1} (Nearest integer)
Given : ΔdisHCl2(g)0=240kJmol−1{\Delta}_{\text{dis}}{H}_{{Cl}_{2 ( g )}}^{0} = 240{kJmol}^{- 1}.
ΔegHCl(g)o=−350kJmol−1{\Delta}_{eg}{H}_{Cl ( g )}^{o} = - 350{kJmol}^{- 1},
ΔhydHCl(g)−o=−380kJmol−1{\Delta}_{hyd}{H}_{{Cl}_{( g )}^{-}}^{o} = - 380{kJmol}^{- 1}

Correct answer

0

Step-by-step solution

12Cl2(g)→Cl(g)→Cl(g)−→Cl(aq.)−\dfrac{1}{2}{Cl}_{2 ( g )} \to {Cl}_{( g )} \to {Cl}_{( g )}^{-} \to {Cl}_{( aq . )}^{-}

Apply Hess's law,

∆H=12∆disHCl2(g)0+∆egHCl(g)o+∆hydHCl(g)−o∆ H = \dfrac{1}{2}{∆}_{dis}{H}_{{Cl}_{2} ( g )}^{0} + {∆}_{eg}{H}_{Cl ( g )}^{o} + {∆}_{hyd}{H}_{{Cl}_{( g )}^{-}}^{o}

⇒∆H=12×240+(−350)+(−380)⇒ ∆ H = \dfrac{1}{2} \times 240 + ( - 350 ) + ( - 380 )

⇒∆H=−610⇒ ∆ H = - 610

Practice Thermodynamics (C) on Quantrex Academy →

More from Thermodynamics (C)

An ideal gas ( 0.5 mol), initially at 2 bar pressure, is compressed at a constant… JEE Advanced 2026List-I contains various physical/chemical processes, and List-II contains combinations of… JEE Advanced 2026Consider the reaction 2H_2S(g) + 3O_2(g) arrow 2H_2O(l) + 2SO_2(g) The magnitude of… JEE Main 2026Match List - I with List - II. Given V_1 and V_2 are initial and final volumes… JEE Main 2026Arrange the following isothermal processes in order of the magnitude of the work ( p - V… JEE Main 2026Consider the reaction X leftharpoons Y at 300 K. If Δ H^ θ and K are 28.40 kJ mol ^ -1… JEE Main 2026Consider the following data for the reaction X_2(g) + Y_2(g) leftharpoons 2XY(g) at 600 K… JEE Main 2026The correct order of molar heat capacities measured at 298 K and 1 bar is : JEE Main 2026 Full Thermodynamics (C) list All JEE Main PYQs