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JEE Main 202227 JulyMorning Shift
Exam
JEE Main
Year
2022
Date
27 July
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2022 · 27 July · Morning Shift · Chemistry · Thermodynamics (C)

The molar heat capacity for an ideal gas at constant pressure is 20...

The molar heat capacity for an ideal gas at constant pressure is 20.785JK−1mol−120 . 785J{K}^{- 1}{mol}^{- 1}. The change in internal energy is 5000J5000J upon heating it from 300K300K to 500K500K. The number of moles of the gas at constant volume is____

(Given: R=8.314JK−1mol−1R = 8 . 314J{K}^{- 1}{mol}^{- 1})

Correct answer

0

Step-by-step solution

Molar specific heat capacity at constant pressure is defined as the amount of heat energy required to raise the temperature of one mole of a substance through 1K1K or 1°C1 ° C at constant pressure. It is denoted by Cp,m{C}_{p, m}.

Molar specific heat capacity at constant volume is defined as the amount of heat energy required to raise the temperature of one mole of a substance through 1K1K or 1°C1 ° C at constant volume. It is denoted by Cv,m{C}_{v, m}.

Cv,m=1n∆U∆T{C}_{v, m} = \dfrac{1}{n}\dfrac{∆ U}{∆ T}

Cp,m=Cv,m+R{C}_{p, m} = {C}_{v, m} + R

⇒Cv,m=20.785−8.314=12.471Jk−1ml−1⇒ {C}_{v, m} = 20 . 785 - 8 . 314 = 12 . 471{Jk}^{- 1}{ml}^{- 1}

ΔU=nCv,mΔT\Delta U = {nC}_{v, m}\Delta T

⇒n=500012.471×200=2512.471≈2⇒ n = \dfrac{5000}{12 . 471 \times 200} = \dfrac{25}{12 . 471} \approx 2

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