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JEE Main 202226 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
26 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2022 · 26 June · Evening Shift · Chemistry · Thermodynamics (C)

A fish swimming in water body when taken out from the water body is...

AA fish swimming in water body when taken out from the water body is covered with a film of water of weight 36g36g. When it is subjected to cooking at 100°C100 ° C, then the internal energy for vaporization in kJmol−1{kJmol}^{- 1} is integer]

[Assume steam to be an ideal gas. Given ΔvapH⊖{\Delta}_{vap}{H}^{⊖} for water at 373K373K and 11 bar is 41.1kJmol−1:R=8.31JK−1mol−141 . 1kJ{mol}^{- 1}: R = 8 . 31J{K}^{- 1}{mol}^{- 1}]

Correct answer

38

Step-by-step solution

Weight of water on fish =36= 36 gram

H2O(l)→P=1barT=100°CH2O(g);ΔHvap=41.1kJmole−1{H}_{2}O\left(l\right)\mathop{\to}_{P = 1bar}^{T = 100 ° C}{H}_{2}O\left(g\right); {\Delta H}_{vap} = 41 . 1kJ{mole}^{- 1}

ΔH=ΔU=ΔngRT\Delta H = \Delta U = {\Delta n}_{g}RT

\left(41 . 1\right) \times 2 = \Delta U + \left(\dfrac{2 \times 8 . 314}{1000}\right)373</p><p></p><p>\Delta U = 82 . 2 - 6 . 2 = 76kJ</p><p>sochangeininternalenergy(inkJ/mol)=762=38kJ/mole</p><p>so change in internal energy \left(inkJ / mol\right) = \dfrac{76}{2} = 38kJ / mole

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