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JIPMER 2019
Exam
JIPMER
Year
2019
Subject
Chemistry
Chapter
Coordination Compounds

JIPMER 2019 · Chemistry · Coordination Compounds

The magnetic moment of Ni^ 2+ ion (atomic number of Ni=28 ) in BM...

The magnetic moment of Ni2+\mathrm{Ni}^{2+} ion (atomic number of Ni=28\mathrm{Ni}=28 ) in BM unit isThe magnetic moment of Ni^ 2+ ion (atomic number of Ni=28 ) in BM unit is

Options

  1. A1.73
  2. B4.81
  3. C5.96
  4. D2.84

Correct answer

D. 2.84

Step-by-step solution

Ni28=[Ar]183 d84 s2,Ni2+=[Ar]183 d84 s2\mathrm{Ni}_{28}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2, \mathrm{Ni}^{2+}=[\mathrm{Ar}]_{18} 3 \mathrm{~d}^8 4 \mathrm{~s}^2 The magnetic moment of Ni^ 2+ ion (atomic number of Ni=28 ) in BM unit is Number of unpaired electrons =2=2 Magnetic moment, μ=n(n+2)=2(2+2)=8=2.84BM\mu=\sqrt{n(n+2)}=\sqrt{2(2+2)}=\sqrt{8}=2.84 \mathrm{BM}
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